1 00:00:13,520 --> 00:00:11,450 just very very briefly i'm going to say 2 00:00:15,470 --> 00:00:13,530 good afternoon to the people watching 3 00:00:18,500 --> 00:00:15,480 and also to anyone who's going to be 4 00:00:21,349 --> 00:00:18,510 watching this are as a recording just a 5 00:00:23,870 --> 00:00:21,359 few aunt min notes to deal with if you 6 00:00:26,210 --> 00:00:23,880 happen to be dialed into this but only 7 00:00:29,900 --> 00:00:26,220 on the audio side you are welcome to 8 00:00:32,900 --> 00:00:29,910 download the slides which are loop 2 in 9 00:00:35,500 --> 00:00:32,910 the event for today on the front of the 10 00:00:37,819 --> 00:00:35,510 website if you've been looking a 11 00:00:41,299 --> 00:00:37,829 document that's the basis of this 12 00:00:43,160 --> 00:00:41,309 presentation in the last day or so it 13 00:00:46,190 --> 00:00:43,170 changed quite significantly and I just 14 00:00:48,560 --> 00:00:46,200 wanted to mention the fact that it was 15 00:00:51,500 --> 00:00:48,570 being edited in a different system we 16 00:00:54,740 --> 00:00:51,510 then uploaded the revised document into 17 00:00:56,959 --> 00:00:54,750 Google Docs the comments that have been 18 00:00:58,970 --> 00:00:56,969 added entered previously therefore 19 00:01:01,580 --> 00:00:58,980 vanished but I wouldn't want anyone to 20 00:01:04,340 --> 00:01:01,590 think that they weren't read it was just 21 00:01:07,070 --> 00:01:04,350 part of the editing cycle the title was 22 00:01:09,140 --> 00:01:07,080 also a new and improved one just in case 23 00:01:11,960 --> 00:01:09,150 anyone was thinking wait is this the one 24 00:01:14,300 --> 00:01:11,970 that I'm is meant to the end and finally 25 00:01:17,179 --> 00:01:14,310 this session is being recorded so 26 00:01:20,240 --> 00:01:17,189 anything that you type or say is going 27 00:01:21,890 --> 00:01:20,250 to be placed on the internet and with 28 00:01:27,920 --> 00:01:21,900 that I think I'm going to pass over to 29 00:01:29,840 --> 00:01:27,930 Mike okay welcome everyone Jamie and I 30 00:01:33,050 --> 00:01:29,850 are going to teen tag on this 31 00:01:36,710 --> 00:01:33,060 presentation and as you some of you 32 00:01:39,550 --> 00:01:36,720 probably know see earlier led a webinar 33 00:01:41,660 --> 00:01:39,560 on the organics that are found in 34 00:01:43,819 --> 00:01:41,670 primitive meteorites particularly 35 00:01:47,749 --> 00:01:43,829 carbonaceous chondrites and also in 36 00:01:50,060 --> 00:01:47,759 commentary samples so for that reason we 37 00:01:54,440 --> 00:01:50,070 didn't delete the word I see from the 38 00:01:57,910 --> 00:01:54,450 title new title but we do really want to 39 00:02:01,179 --> 00:01:57,920 address the issue of where are the major 40 00:02:04,190 --> 00:02:01,189 issues and what do we know about 41 00:02:06,830 --> 00:02:04,200 primitive bodies in the solar system and 42 00:02:07,350 --> 00:02:06,840 their role in delivering organics and 43 00:02:09,779 --> 00:02:07,360 water 44 00:02:13,620 --> 00:02:09,789 to especially the young earth but also 45 00:02:17,300 --> 00:02:13,630 to the other planets such as Mars so 46 00:02:20,390 --> 00:02:17,310 with that we have prepared a number of 47 00:02:23,280 --> 00:02:20,400 graphics here to give you a little more 48 00:02:26,730 --> 00:02:23,290 visual information on things that are 49 00:02:29,310 --> 00:02:26,740 written down in words but probably will 50 00:02:31,230 --> 00:02:29,320 jump over a few of these graphics rather 51 00:02:34,910 --> 00:02:31,240 than discuss it in detail that you will 52 00:02:37,830 --> 00:02:34,920 be able to access those at your will 53 00:02:40,650 --> 00:02:37,840 when your download the presentation and 54 00:02:44,810 --> 00:02:40,660 of course we would invite anyone to 55 00:02:47,130 --> 00:02:44,820 interrupt the remarks at any time 56 00:02:50,220 --> 00:02:47,140 because the whole point here is to gain 57 00:02:52,050 --> 00:02:50,230 new insights from you and also to 58 00:02:55,890 --> 00:02:52,060 discuss the insights that the team is 59 00:03:00,150 --> 00:02:55,900 developed so this particular document 60 00:03:03,150 --> 00:03:00,160 which is on the web now was developed by 61 00:03:06,900 --> 00:03:03,160 the folks whose names you see here any 62 00:03:11,850 --> 00:03:06,910 Fred Paulie Francis dark myself and 63 00:03:13,890 --> 00:03:11,860 Jamie and so the final editing of the 64 00:03:17,460 --> 00:03:13,900 presentation was done by Jamie and 65 00:03:19,830 --> 00:03:17,470 myself as recently as this morning so we 66 00:03:21,979 --> 00:03:19,840 take the full blame and give the credit 67 00:03:26,670 --> 00:03:21,989 to others for what you're about to hear 68 00:03:30,479 --> 00:03:26,680 all right so let's move on now the issue 69 00:03:33,360 --> 00:03:30,489 is what can we say about the S or 70 00:03:35,039 --> 00:03:33,370 biological significance of comets what 71 00:03:37,560 --> 00:03:35,049 was that what was their role and by the 72 00:03:39,600 --> 00:03:37,570 way of course to be rights as well what 73 00:03:42,900 --> 00:03:39,610 was the role in delivering water and 74 00:03:45,660 --> 00:03:42,910 prebiotic organics to early Earth as 75 00:03:48,060 --> 00:03:45,670 you'll see in this outline we're going 76 00:03:52,949 --> 00:03:48,070 to present this morning this afternoon 77 00:03:57,090 --> 00:03:52,959 rather depends where you are the issue 78 00:03:58,500 --> 00:03:57,100 is not so simply resolved because within 79 00:04:01,470 --> 00:03:58,510 the last 10 years there's been a 80 00:04:05,460 --> 00:04:01,480 tremendous revolution that has occurred 81 00:04:07,740 --> 00:04:05,470 in our understanding of the motion of 82 00:04:10,560 --> 00:04:07,750 planets early in the solar system and 83 00:04:12,880 --> 00:04:10,570 the way which that not only mixed the 84 00:04:17,170 --> 00:04:12,890 populations of dry and 85 00:04:19,420 --> 00:04:17,180 icy bodies radially but also then change 86 00:04:22,330 --> 00:04:19,430 the understanding of what was delivered 87 00:04:24,580 --> 00:04:22,340 to terrestrial planets and when that 88 00:04:28,120 --> 00:04:24,590 delivery occurred it's still an evolving 89 00:04:30,310 --> 00:04:28,130 picture so the other part of the problem 90 00:04:34,540 --> 00:04:30,320 is that we really don't have very good 91 00:04:38,950 --> 00:04:34,550 information yet on the taxonomy of these 92 00:04:41,470 --> 00:04:38,960 icy planetesimals because it's only been 93 00:04:44,670 --> 00:04:41,480 the past 20 years that we've really had 94 00:04:46,860 --> 00:04:44,680 the powerful infrared and radio 95 00:04:50,080 --> 00:04:46,870 instruments that can permit us to 96 00:04:53,890 --> 00:04:50,090 quantify the actual organic composition 97 00:04:57,760 --> 00:04:53,900 and water in these various bodies we'll 98 00:05:02,290 --> 00:04:57,770 talk about that for a bit so let's go on 99 00:05:03,880 --> 00:05:02,300 then and begin with the story you have 100 00:05:09,159 --> 00:05:03,890 to remember to use that little arrow 101 00:05:11,920 --> 00:05:09,169 there this chart shows a cartoon of some 102 00:05:14,530 --> 00:05:11,930 of the processes that occurred in the 103 00:05:17,290 --> 00:05:14,540 planet-forming phase actually from the 104 00:05:19,630 --> 00:05:17,300 running running from the collapse of the 105 00:05:23,620 --> 00:05:19,640 natal cloud core and the formation of 106 00:05:26,320 --> 00:05:23,630 the proto solar nebula and then evolving 107 00:05:29,440 --> 00:05:26,330 towards the protoplanetary disk and in 108 00:05:33,010 --> 00:05:29,450 particular there many processes that we 109 00:05:36,700 --> 00:05:33,020 now know occurred at that time some of 110 00:05:39,850 --> 00:05:36,710 them like in is a pointer for a moment 111 00:05:44,230 --> 00:05:39,860 some of them actually involve transport 112 00:05:46,690 --> 00:05:44,240 both radially in and out some involved 113 00:05:50,590 --> 00:05:46,700 transport vertically shown over here is 114 00:05:52,420 --> 00:05:50,600 a circle above the midplane a carrying 115 00:05:55,180 --> 00:05:52,430 material up to the region where UV 116 00:05:57,330 --> 00:05:55,190 optical and x-rays can penetrate and of 117 00:06:00,700 --> 00:05:57,340 course that represents different depths 118 00:06:02,770 --> 00:06:00,710 but there one can actually see a lot of 119 00:06:05,320 --> 00:06:02,780 processing going on in these ways a lot 120 00:06:07,150 --> 00:06:05,330 of laboratory astro chemistry and 121 00:06:10,510 --> 00:06:07,160 chemical physics is going on to 122 00:06:14,290 --> 00:06:10,520 understand these processes but as you 123 00:06:16,540 --> 00:06:14,300 can imagine the taking these kinds of 124 00:06:17,780 --> 00:06:16,550 processes and relating those to what we 125 00:06:20,510 --> 00:06:17,790 now see and kana 126 00:06:22,610 --> 00:06:20,520 and primitive meteorites is a major 127 00:06:24,530 --> 00:06:22,620 story in itself and one that's 128 00:06:28,250 --> 00:06:24,540 developing and will continue to develop 129 00:06:31,300 --> 00:06:28,260 for the next few decades I believe so so 130 00:06:37,280 --> 00:06:31,310 that's part of the picture as well 131 00:06:40,030 --> 00:06:37,290 jumping from the the nebular page to the 132 00:06:43,790 --> 00:06:40,040 point at which the Sun formed about 4.6 133 00:06:45,620 --> 00:06:43,800 billion years ago one of the 134 00:06:48,620 --> 00:06:45,630 developments that occurred just in the 135 00:06:53,480 --> 00:06:48,630 last three years was the development of 136 00:06:57,760 --> 00:06:53,490 a model to describe the migration of 137 00:07:02,180 --> 00:06:57,770 giant planets from the their punitive 138 00:07:05,060 --> 00:07:02,190 formative zones inward towards 1.5 au 139 00:07:08,840 --> 00:07:05,070 and outward again to their current 140 00:07:10,940 --> 00:07:08,850 resident locations the sack actually 141 00:07:16,490 --> 00:07:10,950 occurred within the first hundred 142 00:07:19,730 --> 00:07:16,500 thousand years or so and the dynamical 143 00:07:22,700 --> 00:07:19,740 simulations actually go on until 600k 144 00:07:27,470 --> 00:07:22,710 years but the key point is that Jupiter 145 00:07:29,720 --> 00:07:27,480 and Saturn migrated inward as a result 146 00:07:31,940 --> 00:07:29,730 of gas drag this is all before the gas 147 00:07:33,830 --> 00:07:31,950 cleared the nebula you'll notice it's 148 00:07:36,740 --> 00:07:33,840 long before the formation of the 149 00:07:39,290 --> 00:07:36,750 terrestrial planets and it's long before 150 00:07:41,570 --> 00:07:39,300 the of course the mood forming event 151 00:07:44,210 --> 00:07:41,580 which was roughly 40 to 80 million years 152 00:07:47,090 --> 00:07:44,220 after formation of the earth on 153 00:07:48,860 --> 00:07:47,100 formation of the Sun excuse me the key 154 00:07:52,330 --> 00:07:48,870 point and take home point of this slide 155 00:07:58,640 --> 00:07:52,340 is that if you look at the center panel 156 00:08:00,650 --> 00:07:58,650 the particular card bars are the color 157 00:08:05,120 --> 00:08:00,660 points represent material that was 158 00:08:07,070 --> 00:08:05,130 formed either within about two au of the 159 00:08:10,060 --> 00:08:07,080 Sun or outbound of that so these would 160 00:08:13,120 --> 00:08:10,070 be dry planetesimals 161 00:08:15,160 --> 00:08:13,130 in the former case and I see ones or wet 162 00:08:17,800 --> 00:08:15,170 ones if you like that were formed 163 00:08:22,480 --> 00:08:17,810 farther out this process when Jupiter 164 00:08:25,570 --> 00:08:22,490 actually migrated inwards and then out 165 00:08:28,750 --> 00:08:25,580 again left the this material in the 166 00:08:34,060 --> 00:08:28,760 region of the scattered around in the 167 00:08:37,690 --> 00:08:34,070 region of one to three at you and so it 168 00:08:41,469 --> 00:08:37,700 mixed the dry planetesimals outwards and 169 00:08:43,120 --> 00:08:41,479 the icy winds inward of course the icy 170 00:08:46,510 --> 00:08:43,130 ones would have vaporized or begun to 171 00:08:50,140 --> 00:08:46,520 sublime but if one extends that beyond 172 00:08:52,390 --> 00:08:50,150 this to what happened that as far out of 173 00:08:55,990 --> 00:08:52,400 six and eight a you what it means is 174 00:08:58,900 --> 00:08:56,000 that material that was was mixed and 175 00:09:00,460 --> 00:08:58,910 from one region into another and so this 176 00:09:02,650 --> 00:09:00,470 will play a major role in understanding 177 00:09:06,880 --> 00:09:02,660 what was delivered to the growing 178 00:09:09,910 --> 00:09:06,890 proto-earth proto mars and so on but 179 00:09:13,570 --> 00:09:09,920 also in what role later developments had 180 00:09:15,190 --> 00:09:13,580 toward subsequently delivery material to 181 00:09:17,410 --> 00:09:15,200 the altar estrella planets and of course 182 00:09:20,020 --> 00:09:17,420 we need to know the nature of these 183 00:09:24,280 --> 00:09:20,030 bodies in order to assess what it was 184 00:09:26,680 --> 00:09:24,290 that could have delivered ok so the 185 00:09:29,170 --> 00:09:26,690 grant sack is this is called actually 186 00:09:32,020 --> 00:09:29,180 succeeds in predicting a low-mass mars 187 00:09:34,540 --> 00:09:32,030 and most other models do not succeed at 188 00:09:37,480 --> 00:09:34,550 that so this has given it more than just 189 00:09:40,870 --> 00:09:37,490 casual acceptance within the community 190 00:09:44,670 --> 00:09:40,880 we don't know that it's fully correct so 191 00:09:49,900 --> 00:09:44,680 on these are course developing things so 192 00:09:54,580 --> 00:09:49,910 let's move on a bit after formation of 193 00:09:56,650 --> 00:09:54,590 the planetary system let's call that to 194 00:09:59,740 --> 00:09:56,660 be at around 100 million years at 195 00:10:02,220 --> 00:09:59,750 formation of the Sun a separate 196 00:10:05,080 --> 00:10:02,230 dynamical model called the nice model 197 00:10:08,500 --> 00:10:05,090 actually predicts the dynamical 198 00:10:10,720 --> 00:10:08,510 evolution of the outer planet region and 199 00:10:13,060 --> 00:10:10,730 roots begins at 100 million years with 200 00:10:15,430 --> 00:10:13,070 the outer planets now and they're 201 00:10:18,510 --> 00:10:15,440 approximately their their current 202 00:10:20,820 --> 00:10:18,520 locations between 5 and 14 astronaut 203 00:10:23,220 --> 00:10:20,830 good units and they were in the order of 204 00:10:26,550 --> 00:10:23,230 Jupiter Saturn Neptune and then Uranus 205 00:10:29,580 --> 00:10:26,560 Neptune wind-up tune inside because you 206 00:10:32,100 --> 00:10:29,590 need to make neptr Oh Neptune in within 207 00:10:33,720 --> 00:10:32,110 that hundred million year interval and 208 00:10:36,930 --> 00:10:33,730 it's difficult to do it if it's very far 209 00:10:39,630 --> 00:10:36,940 away but even Uranus was only 14 AU from 210 00:10:43,160 --> 00:10:39,640 the protosun from the Sun at that time 211 00:10:45,870 --> 00:10:43,170 there also was an icy disk planetesimals 212 00:10:48,300 --> 00:10:45,880 and of course as we now know from the 213 00:10:49,860 --> 00:10:48,310 previous slide this disk probably also 214 00:10:52,980 --> 00:10:49,870 contains some material that have been 215 00:10:55,530 --> 00:10:52,990 injected outward from the dry region of 216 00:11:00,480 --> 00:10:55,540 the protoplanetary disk 2 1 2 3 au 217 00:11:03,500 --> 00:11:00,490 region then as Jupiter Saturn migrated 218 00:11:06,960 --> 00:11:03,510 to their tutor one knee motion residents 219 00:11:11,700 --> 00:11:06,970 by ejection of planetesimals and they're 220 00:11:14,280 --> 00:11:11,710 feeding zones they basically caused a 221 00:11:18,420 --> 00:11:14,290 destabilization of the disk at around 222 00:11:21,690 --> 00:11:18,430 3.8 billion years ago in which Neptune 223 00:11:24,750 --> 00:11:21,700 and Uranus now switch places and the 224 00:11:28,170 --> 00:11:24,760 outer disk is destabilized so is the 225 00:11:29,940 --> 00:11:28,180 inner asteroid belt and both of these 226 00:11:32,460 --> 00:11:29,950 classes of bodies then are flung through 227 00:11:34,410 --> 00:11:32,470 the solar system with the icy bodies 228 00:11:36,900 --> 00:11:34,420 going primarily into forming the Kuiper 229 00:11:38,820 --> 00:11:36,910 disk or out to the Oort cloud and of 230 00:11:40,740 --> 00:11:38,830 course many of the asteroids and many of 231 00:11:42,900 --> 00:11:40,750 these bodies me iso disk would then be 232 00:11:45,330 --> 00:11:42,910 flown through the inner solar system and 233 00:11:48,090 --> 00:11:45,340 would bombard the terrestrial planets so 234 00:11:51,540 --> 00:11:48,100 again this this model dynamical model 235 00:11:53,880 --> 00:11:51,550 which has achieved success by resolving 236 00:11:57,270 --> 00:11:53,890 the explanations for about eight or nine 237 00:11:59,910 --> 00:11:57,280 major conundrums about the giant planets 238 00:12:01,770 --> 00:11:59,920 themselves and also their companion 239 00:12:05,490 --> 00:12:01,780 bodies such as the Trojan asteroids and 240 00:12:07,470 --> 00:12:05,500 so on has achieved great acceptance 241 00:12:09,570 --> 00:12:07,480 within the community and so challenge it 242 00:12:13,680 --> 00:12:09,580 presents for this particular webinar is 243 00:12:16,440 --> 00:12:13,690 to keep in mind the grand tack the beast 244 00:12:18,840 --> 00:12:16,450 model I didn't mention the birth cluster 245 00:12:20,790 --> 00:12:18,850 model for origin of the some knob 246 00:12:23,030 --> 00:12:20,800 placement somebody's in the Oort cloud 247 00:12:26,040 --> 00:12:23,040 during the in the son's birth cluster 248 00:12:27,090 --> 00:12:26,050 but these three dynamical models 249 00:12:30,600 --> 00:12:27,100 together have 250 00:12:33,300 --> 00:12:30,610 we change the picture dramatically as to 251 00:12:36,270 --> 00:12:33,310 what we need to know about the primitive 252 00:12:38,490 --> 00:12:36,280 planetesimals and then also their 253 00:12:40,920 --> 00:12:38,500 dynamical delivery and the numbers that 254 00:12:44,550 --> 00:12:40,930 were delivered at various times to the 255 00:12:46,230 --> 00:12:44,560 young earth for example so the issue 256 00:12:49,680 --> 00:12:46,240 then is since that we know they're rich 257 00:12:51,810 --> 00:12:49,690 in organic sandwich in water could they 258 00:12:53,640 --> 00:12:51,820 have delivered those materials to the 259 00:12:55,920 --> 00:12:53,650 terrestrial planets and sufficient 260 00:13:00,660 --> 00:12:55,930 abundance to have influenced the 261 00:13:02,460 --> 00:13:00,670 emergence of life itself okay so let's 262 00:13:04,980 --> 00:13:02,470 move on maybe a lot of things to talk 263 00:13:07,080 --> 00:13:04,990 about so this just reminds you of the 264 00:13:10,320 --> 00:13:07,090 reservoirs today I won't go into that in 265 00:13:12,750 --> 00:13:10,330 detail they're basically two for sure 266 00:13:16,050 --> 00:13:12,760 that namely IG bodies reside in your 267 00:13:19,500 --> 00:13:16,060 cloud in the Kuiper disk and there may 268 00:13:22,890 --> 00:13:19,510 be met some in the main belt as well and 269 00:13:25,530 --> 00:13:22,900 we can look to the grand tack as the 270 00:13:27,390 --> 00:13:25,540 reason why they might be there but we 271 00:13:30,330 --> 00:13:27,400 don't actually have any detection of 272 00:13:33,030 --> 00:13:30,340 water vapor or any other gas released 273 00:13:34,860 --> 00:13:33,040 from any of these active asteroids so 274 00:13:36,990 --> 00:13:34,870 it's not clear yet whether those 275 00:13:39,300 --> 00:13:37,000 asteroids are activated by collisions or 276 00:13:42,090 --> 00:13:39,310 whether some actually are activated by 277 00:13:45,990 --> 00:13:42,100 water and when the asteroid moves 278 00:13:47,790 --> 00:13:46,000 towards its perihelion spizz ition okay 279 00:13:51,390 --> 00:13:47,800 so how do we get at these questions 280 00:13:53,910 --> 00:13:51,400 about the material that is contained 281 00:13:55,500 --> 00:13:53,920 within commentary bodies and these icy 282 00:13:58,200 --> 00:13:55,510 planetesimals and how that might be 283 00:14:01,350 --> 00:13:58,210 delivered to earth well this is just a 284 00:14:03,240 --> 00:14:01,360 take-home message which says you really 285 00:14:06,750 --> 00:14:03,250 don't learn much about the composition 286 00:14:08,040 --> 00:14:06,760 by looking at an image of the object you 287 00:14:10,920 --> 00:14:08,050 know you just learn something about us 288 00:14:14,690 --> 00:14:10,930 it's a history for example this this 289 00:14:17,540 --> 00:14:14,700 object is heavily eroded by mass loss 290 00:14:21,900 --> 00:14:17,550 whereas something like build to 291 00:14:24,660 --> 00:14:21,910 nucleuses as enormous vertical structure 292 00:14:26,790 --> 00:14:24,670 hundreds of meters spires hundreds of 293 00:14:29,220 --> 00:14:26,800 meters of high and so forth and it's 294 00:14:31,440 --> 00:14:29,230 thought to be a pristine not heavily 295 00:14:34,710 --> 00:14:31,450 eroded since it was placed in its 296 00:14:35,519 --> 00:14:34,720 present orbit so what instead one needs 297 00:14:38,309 --> 00:14:35,529 to do is 298 00:14:41,579 --> 00:14:38,319 to begin to look at the chemicals of 299 00:14:44,699 --> 00:14:41,589 which these objects are made and one of 300 00:14:46,860 --> 00:14:44,709 the first Clues it was quantitated 301 00:14:50,699 --> 00:14:46,870 quantitatively derived a taxonomy if you 302 00:14:53,960 --> 00:14:50,709 like was based on not the the primary or 303 00:14:56,160 --> 00:14:53,970 native volatiles from which comets are 304 00:14:59,850 --> 00:14:56,170 composed because when this work was done 305 00:15:03,299 --> 00:14:59,860 it was not possible to measure those one 306 00:15:05,759 --> 00:15:03,309 could only measure the fragments that 307 00:15:08,249 --> 00:15:05,769 derived from those molecules and so C 2 308 00:15:11,549 --> 00:15:08,259 and C n are bright and easily seen in 309 00:15:14,249 --> 00:15:11,559 the optical and so a team led by Mike 310 00:15:17,400 --> 00:15:14,259 Ahern and his collaborators basically 311 00:15:19,439 --> 00:15:17,410 quantified the ratio of c2 CN at number 312 00:15:20,910 --> 00:15:19,449 of comets and showed that for comets 313 00:15:23,730 --> 00:15:20,920 from the Kuiper belt they seem to be 314 00:15:26,910 --> 00:15:23,740 sufficient substantially depleted in 315 00:15:29,369 --> 00:15:26,920 this ratio whereas relatively a smaller 316 00:15:31,829 --> 00:15:29,379 number of Oort cloud comets were so 317 00:15:34,429 --> 00:15:31,839 depleted so this was indication was 318 00:15:37,679 --> 00:15:34,439 suggested that this could be perhaps a 319 00:15:39,059 --> 00:15:37,689 cosmic ganic difference although other 320 00:15:40,920 --> 00:15:39,069 people thought maybe it was due to 321 00:15:43,259 --> 00:15:40,930 processing because of Jupiter family 322 00:15:44,850 --> 00:15:43,269 comments from the Kuiper belt have been 323 00:15:48,809 --> 00:15:44,860 in their orbits for a long time whereas 324 00:15:51,629 --> 00:15:48,819 many of your cloud comets it not so it 325 00:15:56,699 --> 00:15:51,639 also dramatized need for looking at the 326 00:15:59,240 --> 00:15:56,709 individual parent or primary of all 327 00:16:02,549 --> 00:15:59,250 sizes we don't like to call them and 328 00:16:06,569 --> 00:16:02,559 this chart reminds you of the two dozen 329 00:16:11,519 --> 00:16:06,579 or so primary volatiles which have now 330 00:16:13,049 --> 00:16:11,529 been detected in commentary bodies when 331 00:16:14,999 --> 00:16:13,059 they've been vaporized and entered 332 00:16:17,480 --> 00:16:15,009 Tacoma there in the gas phase and they 333 00:16:20,309 --> 00:16:17,490 are then amenable to detection by 334 00:16:23,069 --> 00:16:20,319 looking at their rotation vibrational 335 00:16:25,679 --> 00:16:23,079 emissions or the rotational emissions at 336 00:16:30,990 --> 00:16:25,689 infrared and radio wavelengths 337 00:16:33,509 --> 00:16:31,000 respectively so what's shown here is two 338 00:16:35,429 --> 00:16:33,519 things one is the range of species water 339 00:16:38,009 --> 00:16:35,439 being at the top but the other is the 340 00:16:40,610 --> 00:16:38,019 range of abundance in it given nucleus 341 00:16:43,060 --> 00:16:40,620 and what you see immediately is that 342 00:16:46,480 --> 00:16:43,070 whenever water is used as a mess 343 00:16:48,550 --> 00:16:46,490 Rick you see huge range of abundance of 344 00:16:52,390 --> 00:16:48,560 for example co by a factor of a hundred 345 00:16:55,720 --> 00:16:52,400 in going from one body to another and in 346 00:16:58,450 --> 00:16:55,730 co2 almost a factor of 20 and so on 347 00:17:02,680 --> 00:16:58,460 whereas other molecules show a much 348 00:17:05,020 --> 00:17:02,690 smaller gradient for example hcs there 349 00:17:07,870 --> 00:17:05,030 is by about a factor of 5 and so on we 350 00:17:09,640 --> 00:17:07,880 don't understand this yet we think 351 00:17:11,800 --> 00:17:09,650 perhaps it may be in some cases 352 00:17:13,960 --> 00:17:11,810 cosmogonic and that's of course one of 353 00:17:16,750 --> 00:17:13,970 the key issues in understanding how to 354 00:17:18,220 --> 00:17:16,760 relate these measurements to delivery 355 00:17:22,530 --> 00:17:18,230 from different regions of the 356 00:17:26,650 --> 00:17:22,540 protoplanetary disk to young planets and 357 00:17:31,510 --> 00:17:26,660 delivery goes to the atmospheric content 358 00:17:32,980 --> 00:17:31,520 of those particular objects well I'm 359 00:17:34,900 --> 00:17:32,990 going to skip over this so you can go 360 00:17:38,800 --> 00:17:34,910 back and look at this later this is from 361 00:17:40,210 --> 00:17:38,810 the Akari space observatory and for some 362 00:17:44,430 --> 00:17:40,220 reason I just seem to go into full 363 00:17:46,630 --> 00:17:44,440 screen display here okay that's good and 364 00:17:48,640 --> 00:17:46,640 the key point is that this was a 365 00:17:51,280 --> 00:17:48,650 paradigm shift and our understanding of 366 00:17:54,340 --> 00:17:51,290 comets and occurred the paper was 367 00:17:56,500 --> 00:17:54,350 published in 2012 a half j and until 368 00:17:58,870 --> 00:17:56,510 then no one really understood that co2 369 00:18:01,480 --> 00:17:58,880 was so important relative to water or 370 00:18:05,070 --> 00:18:01,490 that it was so more much more abundant 371 00:18:08,170 --> 00:18:05,080 than co this was a major surprise and 372 00:18:10,300 --> 00:18:08,180 there was some indication from 373 00:18:14,200 --> 00:18:10,310 interstellar chemistry this would be so 374 00:18:16,120 --> 00:18:14,210 but it's generally not clear the degree 375 00:18:18,220 --> 00:18:16,130 to which comets are made of interstellar 376 00:18:20,320 --> 00:18:18,230 material so we don't know whether this 377 00:18:22,300 --> 00:18:20,330 co2 is a heritage of the interstellar 378 00:18:24,400 --> 00:18:22,310 medium or whether it was something that 379 00:18:26,470 --> 00:18:24,410 was easily produced in the 380 00:18:28,690 --> 00:18:26,480 protoplanetary disk for example 381 00:18:30,850 --> 00:18:28,700 reactions between co and 0 h radicals 382 00:18:33,190 --> 00:18:30,860 produce co2 and every collision 383 00:18:35,890 --> 00:18:33,200 essentially and then you can condense 384 00:18:40,750 --> 00:18:35,900 that co2 rapidly on a grain and enter it 385 00:18:44,620 --> 00:18:40,760 into a comet nucleus and this could be ! 386 00:18:47,260 --> 00:18:44,630 issue key point is the simultaneity of 387 00:18:48,290 --> 00:18:47,270 measurement and what you really want to 388 00:18:50,090 --> 00:18:48,300 do and this is 389 00:18:52,360 --> 00:18:50,100 is done at infrared wavelengths is to 390 00:18:55,190 --> 00:18:52,370 measure a whole suite of molecule 391 00:18:57,470 --> 00:18:55,200 simultaneously shown on the left here 392 00:18:58,940 --> 00:18:57,480 you see approximately nine molecules 393 00:19:01,580 --> 00:18:58,950 that are measured routinely in every 394 00:19:03,980 --> 00:19:01,590 comet and then others is a total logs 395 00:19:05,840 --> 00:19:03,990 which are more difficult to measure and 396 00:19:09,830 --> 00:19:05,850 they are also targeted as well in common 397 00:19:12,800 --> 00:19:09,840 too common so this gives you the power 398 00:19:14,720 --> 00:19:12,810 to assess how the material is 399 00:19:16,790 --> 00:19:14,730 distributed within the cometary nucleus 400 00:19:19,310 --> 00:19:16,800 by looking at how it's actually 401 00:19:22,040 --> 00:19:19,320 distributed and coming off in the coma 402 00:19:24,920 --> 00:19:22,050 if you see the a polar species coming in 403 00:19:26,300 --> 00:19:24,930 one direction on the polar species in a 404 00:19:28,970 --> 00:19:26,310 different direction from the nucleus 405 00:19:30,680 --> 00:19:28,980 that suggests strongly that they're two 406 00:19:32,750 --> 00:19:30,690 distinct types phases that are not 407 00:19:35,270 --> 00:19:32,760 hitter at home ingeniously mixed within 408 00:19:37,640 --> 00:19:35,280 the nucleus and we do indeed see that in 409 00:19:41,620 --> 00:19:37,650 some comments so that is another part of 410 00:19:45,710 --> 00:19:41,630 the puzzle I'll just to dramatize this 411 00:19:48,820 --> 00:19:45,720 created this cartoon which compares 412 00:19:52,160 --> 00:19:48,830 three Oort cloud comets and everyone 413 00:19:53,690 --> 00:19:52,170 people who don't study comments tend to 414 00:19:55,390 --> 00:19:53,700 think everything in the Oort cloud is 415 00:19:59,630 --> 00:19:55,400 the same in terms of its composition 416 00:20:01,450 --> 00:19:59,640 everything in the Hartley oh I'm sorry 417 00:20:04,490 --> 00:20:01,460 in the Kuiper belt is the same and so on 418 00:20:06,530 --> 00:20:04,500 but if you look at this so it's at the 419 00:20:10,220 --> 00:20:06,540 low end of the diet of the diagram you 420 00:20:14,020 --> 00:20:10,230 see this a particular depiction of the 421 00:20:16,700 --> 00:20:14,030 overall composition of the comet here 422 00:20:18,920 --> 00:20:16,710 where the blue represents the water 423 00:20:20,510 --> 00:20:18,930 vapor and the trace gases are everything 424 00:20:23,660 --> 00:20:20,520 else in the small wedge that's just 425 00:20:26,390 --> 00:20:23,670 above that but if you break that the 426 00:20:28,820 --> 00:20:26,400 trace gas is down comment by comet then 427 00:20:32,080 --> 00:20:28,830 for Hartley 2 for example you find that 428 00:20:35,840 --> 00:20:32,090 co2 comprised almost eighty percent of 429 00:20:38,600 --> 00:20:35,850 the trace gas whereas for garad it was 430 00:20:40,370 --> 00:20:38,610 about a third and four luling about the 431 00:20:42,590 --> 00:20:40,380 same so here you see a dramatic 432 00:20:45,050 --> 00:20:42,600 difference in these three comets from 433 00:20:46,130 --> 00:20:45,060 the same reservoir clearly indicating 434 00:20:49,160 --> 00:20:46,140 that they're quite different their 435 00:20:51,830 --> 00:20:49,170 composition so again if you look at 436 00:20:53,990 --> 00:20:51,840 other molecules different differentiated 437 00:20:55,310 --> 00:20:54,000 by these colors you can see for example 438 00:20:57,560 --> 00:20:55,320 a huge 439 00:21:00,230 --> 00:20:57,570 difference in this particular species as 440 00:21:03,560 --> 00:21:00,240 you go from comet comet to comment so 441 00:21:05,450 --> 00:21:03,570 this is a clear indication of perhaps 442 00:21:07,640 --> 00:21:05,460 they were formed in different regions of 443 00:21:09,140 --> 00:21:07,650 the pillow contrary disk or incorporated 444 00:21:12,080 --> 00:21:09,150 material formed in those different 445 00:21:14,860 --> 00:21:12,090 regions and so on this is part of the 446 00:21:18,500 --> 00:21:14,870 puzzle that we need to get two answers 447 00:21:22,430 --> 00:21:18,510 okay so I've kind of mentioned several 448 00:21:25,610 --> 00:21:22,440 of these paradigm shifts have occurred 449 00:21:27,890 --> 00:21:25,620 in very recent time that are informing 450 00:21:29,780 --> 00:21:27,900 us about the nature of these bodies and 451 00:21:32,300 --> 00:21:29,790 how they can relate to understanding 452 00:21:37,160 --> 00:21:32,310 their role in delivering such material 453 00:21:40,550 --> 00:21:37,170 to the young planets now we've tried to 454 00:21:42,050 --> 00:21:40,560 group these commentary bodies the 455 00:21:44,300 --> 00:21:42,060 infrared teams have together put 456 00:21:49,790 --> 00:21:44,310 together approximately database on 457 00:21:52,520 --> 00:21:49,800 roughly 25 to 30 comments and for the 458 00:21:56,570 --> 00:21:52,530 ones that are best characterized we're 459 00:21:59,870 --> 00:21:56,580 able to show that in fact the ethane for 460 00:22:02,600 --> 00:21:59,880 example if one just shows the number of 461 00:22:04,610 --> 00:22:02,610 comets and the versus the abundance of 462 00:22:06,290 --> 00:22:04,620 ethane relative to water you can see 463 00:22:08,090 --> 00:22:06,300 this is a real clumping in this area at 464 00:22:10,460 --> 00:22:08,100 around point six percent relative to 465 00:22:12,680 --> 00:22:10,470 water but there are several comments 466 00:22:15,380 --> 00:22:12,690 that are highly enriched by factors of 467 00:22:17,720 --> 00:22:15,390 two or so and others that are not we 468 00:22:21,710 --> 00:22:17,730 depleted and we see the same thing and 469 00:22:26,260 --> 00:22:21,720 methanol both or normal as we call it 470 00:22:30,409 --> 00:22:26,270 enriched and depleted if one moves on to 471 00:22:35,389 --> 00:22:30,419 look at these order the is actually 472 00:22:42,169 --> 00:22:35,399 17 different things either steal lemons 473 00:22:43,820 --> 00:22:42,179 review what is he someone dude please 474 00:22:50,690 --> 00:22:43,830 are getting a lot of pick up on a mic 475 00:22:53,180 --> 00:22:50,700 consumer sorry about that Mike I'm is 476 00:22:57,379 --> 00:22:53,190 going to meet that line for now okay 477 00:22:59,479 --> 00:22:57,389 thanks the green region represents CEO 478 00:23:01,039 --> 00:22:59,489 rich comets which are as you see they're 479 00:23:05,149 --> 00:23:01,049 rare in this population we only have 480 00:23:08,359 --> 00:23:05,159 four of them a total of the 18 display 481 00:23:10,729 --> 00:23:08,369 here so less than 20 about a quarter or 482 00:23:13,759 --> 00:23:10,739 perhaps twenty percent of the comments 483 00:23:15,849 --> 00:23:13,769 or CEO rich but once when you look for 484 00:23:18,680 --> 00:23:15,859 correlations of molecule to molecule 485 00:23:19,970 --> 00:23:18,690 really the thing that jumps out at you 486 00:23:24,349 --> 00:23:19,980 if you look at this for a little while 487 00:23:26,720 --> 00:23:24,359 is it hcn is correlated with ethane but 488 00:23:28,909 --> 00:23:26,730 not with CEO and not with methane for 489 00:23:30,769 --> 00:23:28,919 example and so this suggests that 490 00:23:32,029 --> 00:23:30,779 looking at different comets in there in 491 00:23:34,249 --> 00:23:32,039 the correlation of these two molecules 492 00:23:36,590 --> 00:23:34,259 might in fact reveal some new 493 00:23:41,499 --> 00:23:36,600 information and sure enough when you do 494 00:23:44,180 --> 00:23:41,509 that you see that again the three bodies 495 00:23:46,609 --> 00:23:44,190 there's a group that has a high ratio 496 00:23:50,570 --> 00:23:46,619 for both this is could be regarded as a 497 00:23:52,519 --> 00:23:50,580 mixing line but most comets are down in 498 00:23:55,129 --> 00:23:52,529 this region of the mixing line only a 499 00:23:59,239 --> 00:23:55,139 few are up at the high end and there are 500 00:24:03,169 --> 00:23:59,249 a few of roads if you like which have 501 00:24:05,149 --> 00:24:03,179 very little f ain but a lot of hcn we 502 00:24:09,109 --> 00:24:05,159 think this is a different group of 503 00:24:11,119 --> 00:24:09,119 comets we've called them depleted comets 504 00:24:12,979 --> 00:24:11,129 but we think there is another story 505 00:24:15,859 --> 00:24:12,989 behind this and we're trying to unravel 506 00:24:21,529 --> 00:24:15,869 with the line of evidence that we have a 507 00:24:24,200 --> 00:24:21,539 half perhaps these are formed the HCM in 508 00:24:26,299 --> 00:24:24,210 some comments is actually not a primary 509 00:24:30,379 --> 00:24:26,309 species that Rather's formed in the coma 510 00:24:31,369 --> 00:24:30,389 by some mechanisms well let's move on we 511 00:24:33,169 --> 00:24:31,379 don't really want to get into the 512 00:24:37,340 --> 00:24:33,179 details of all this just to give you the 513 00:24:39,710 --> 00:24:37,350 broad brush overview another key metric 514 00:24:41,240 --> 00:24:39,720 we look at cosmogonic parameters 515 00:24:44,720 --> 00:24:41,250 these are things we think remain 516 00:24:47,260 --> 00:24:44,730 unchanged from the time of formation the 517 00:24:49,580 --> 00:24:47,270 you know any molecule that has 518 00:24:51,409 --> 00:24:49,590 symmetrically located hydrogen atoms 519 00:24:53,779 --> 00:24:51,419 will have nuclear spins that can be 520 00:24:57,620 --> 00:24:53,789 aligned or anti aligned and under 521 00:25:00,710 --> 00:24:57,630 exchange those things are in that ratios 522 00:25:03,320 --> 00:25:00,720 invariant so this gives rise to a 523 00:25:05,480 --> 00:25:03,330 temperature which one can call the 524 00:25:07,039 --> 00:25:05,490 nuclear spin temperature and the key 525 00:25:10,669 --> 00:25:07,049 point is that if one looks at different 526 00:25:13,520 --> 00:25:10,679 primaries such as ammonia shown here the 527 00:25:16,820 --> 00:25:13,530 ortho para ratio for ammonia and various 528 00:25:19,130 --> 00:25:16,830 comets approaches the equilibrium value 529 00:25:21,710 --> 00:25:19,140 at temperatures above about 35 Kelvin 530 00:25:25,399 --> 00:25:21,720 water approaches a different value this 531 00:25:27,950 --> 00:25:25,409 curve and also can be equilibrated 532 00:25:30,049 --> 00:25:27,960 roughly 50 Calvin but if you take the 533 00:25:31,399 --> 00:25:30,059 temp and spin temperatures and compare 534 00:25:34,159 --> 00:25:31,409 the one with another in these two 535 00:25:37,399 --> 00:25:34,169 species within a given comet what's 536 00:25:39,890 --> 00:25:37,409 remarkable is that they clump in a very 537 00:25:42,620 --> 00:25:39,900 narrow region of this temper at this 538 00:25:44,830 --> 00:25:42,630 space and so this tells you that these 539 00:25:47,840 --> 00:25:44,840 independent molecular species are 540 00:25:50,330 --> 00:25:47,850 registering a same nuclear spin 541 00:25:52,490 --> 00:25:50,340 temperature even though their 542 00:25:54,830 --> 00:25:52,500 chemistry's are significantly different 543 00:25:56,710 --> 00:25:54,840 and we think that's a very important 544 00:25:59,029 --> 00:25:56,720 clue into the formation mechanism 545 00:26:03,289 --> 00:25:59,039 another thing it's very hard to change 546 00:26:06,430 --> 00:26:03,299 in these Isis is the isotopic ratios and 547 00:26:08,840 --> 00:26:06,440 the key thing there is to look at the 548 00:26:11,299 --> 00:26:08,850 ideally the isotopes and individual 549 00:26:13,640 --> 00:26:11,309 species so we'll take a quick look at 550 00:26:16,899 --> 00:26:13,650 what is known at one or two of these 551 00:26:21,620 --> 00:26:16,909 isotopes in particular nitrogen carbon 552 00:26:24,860 --> 00:26:21,630 and hydrogen so for example here is a 553 00:26:28,399 --> 00:26:24,870 survey done by Manfred Shaheen and their 554 00:26:30,950 --> 00:26:28,409 collaborators and for 18 comets they 555 00:26:33,470 --> 00:26:30,960 showed that the carbon 12 13 ratio 556 00:26:35,240 --> 00:26:33,480 measured in situ or cm and by the way 557 00:26:38,060 --> 00:26:35,250 keep in mind these are minor 558 00:26:40,430 --> 00:26:38,070 constituents there are fragments of may 559 00:26:43,640 --> 00:26:40,440 be produced in part from dust we really 560 00:26:46,649 --> 00:26:43,650 don't know all the origins of these two 561 00:26:49,049 --> 00:26:46,659 radicals but the bottom line is that 562 00:26:51,719 --> 00:26:49,059 the mean mean value is in good agreement 563 00:26:55,200 --> 00:26:51,729 with the terrestrial ratio for carbon-12 564 00:26:57,839 --> 00:26:55,210 carbon-13 is that true for nitrogen no 565 00:27:00,599 --> 00:26:57,849 it's not in fact the earth itself is 566 00:27:03,899 --> 00:27:00,609 enriched dramatically relative to the 567 00:27:07,979 --> 00:27:03,909 cosmic value by a factor of two and the 568 00:27:12,180 --> 00:27:07,989 Comets are enriched in that ratio 14 15 569 00:27:14,009 --> 00:27:12,190 and by another factor of two so the 1459 570 00:27:17,789 --> 00:27:14,019 ratio is about a hundred and forty in 571 00:27:20,759 --> 00:27:17,799 the mean there's been no explanation for 572 00:27:22,200 --> 00:27:20,769 this Nora's have been any explanation 573 00:27:25,409 --> 00:27:22,210 for the enrichment of the earth itself 574 00:27:28,080 --> 00:27:25,419 in terms of nitrogen vers versus the 575 00:27:30,509 --> 00:27:28,090 cosmic value so this represents a puzzle 576 00:27:32,039 --> 00:27:30,519 as to why the Comets are different from 577 00:27:35,099 --> 00:27:32,049 the earth did they have a role in 578 00:27:36,839 --> 00:27:35,109 enhancing the earth above the nebular 579 00:27:39,869 --> 00:27:36,849 value is that the the reason the earth 580 00:27:42,719 --> 00:27:39,879 is high in nitrogen 14 verse 15 ratio or 581 00:27:44,849 --> 00:27:42,729 not Mike it looks like penny may have 582 00:27:49,109 --> 00:27:44,859 raised your hand oh we have a hand 583 00:27:50,460 --> 00:27:49,119 raised light up no it's gone no penny 584 00:27:53,190 --> 00:27:50,470 the lines are open if you want to speak 585 00:27:56,609 --> 00:27:53,200 over the phone okay thanks um yeah I was 586 00:28:00,119 --> 00:27:56,619 just wondering you know what extent 587 00:28:03,330 --> 00:28:00,129 would we multiple EC the preservation of 588 00:28:07,369 --> 00:28:03,340 you were just addressing the relative 589 00:28:09,960 --> 00:28:07,379 isotope in rock record of highly 590 00:28:12,710 --> 00:28:09,970 geologically active bodies holder forces 591 00:28:15,060 --> 00:28:12,720 what we might see in much less 592 00:28:18,169 --> 00:28:15,070 geologically active bodies like the 593 00:28:20,700 --> 00:28:18,179 surfaces of icy moon yeah I think 594 00:28:22,440 --> 00:28:20,710 probably Jamie's better qualified to 595 00:28:25,649 --> 00:28:22,450 talk to the meteoritic record on that 596 00:28:28,440 --> 00:28:25,659 yeah but as far as geologically I'd your 597 00:28:33,779 --> 00:28:28,450 body's I don't have much to say about 598 00:28:37,830 --> 00:28:33,789 that okay a good question yeah so penny 599 00:28:41,249 --> 00:28:37,840 I don't know that actually have not 600 00:28:45,509 --> 00:28:41,259 myself looked at the literature as to 601 00:28:48,719 --> 00:28:45,519 the where that terrestrial ratio comes 602 00:28:50,729 --> 00:28:48,729 from of course as we all know nitrogen 603 00:28:51,289 --> 00:28:50,739 gas is the principal carrier in the 604 00:28:53,600 --> 00:28:51,299 atmos 605 00:28:57,019 --> 00:28:53,610 but I have not looked at what's what the 606 00:29:00,950 --> 00:28:57,029 rock record tells us perhaps unwelcome I 607 00:29:03,619 --> 00:29:00,960 could could clarify that point wells in 608 00:29:07,989 --> 00:29:03,629 Helena and it seems like an tme that 609 00:29:11,029 --> 00:29:07,999 maybe this is you know you know in which 610 00:29:13,340 --> 00:29:11,039 some group within the asteroid you've 611 00:29:15,619 --> 00:29:13,350 ever happens I'll be looking at it but I 612 00:29:18,019 --> 00:29:15,629 haven't read every single paper so i'm 613 00:29:20,629 --> 00:29:18,029 not sure if anybody else has books with 614 00:29:23,979 --> 00:29:20,639 that issue that it seems it's important 615 00:29:27,859 --> 00:29:23,989 to try to see what if anything of that 616 00:29:30,680 --> 00:29:27,869 more influence of these these potential 617 00:29:33,229 --> 00:29:30,690 grocery deliveries to the early Earth 618 00:29:35,210 --> 00:29:33,239 may have been preserved in the rock 619 00:29:38,570 --> 00:29:35,220 record than I are or where we cannot 620 00:29:40,159 --> 00:29:38,580 expect to actually people well I guess 621 00:29:42,919 --> 00:29:40,169 if one wants to go back to the 622 00:29:45,289 --> 00:29:42,929 moon-forming event you know you could 623 00:29:47,299 --> 00:29:45,299 argue this has been argued by various 624 00:29:50,060 --> 00:29:47,309 people that significant fraction of the 625 00:29:53,090 --> 00:29:50,070 outgassing of the earth had occurred by 626 00:29:55,909 --> 00:29:53,100 then and a lot of that primordial 627 00:29:59,869 --> 00:29:55,919 atmosphere was removed but during that 628 00:30:02,359 --> 00:29:59,879 collision Mike and so then if you 629 00:30:05,090 --> 00:30:02,369 deliver a new atmosphere you would think 630 00:30:07,789 --> 00:30:05,100 that or at least augmented dramatically 631 00:30:09,649 --> 00:30:07,799 then you would think that the nitrogen 632 00:30:11,599 --> 00:30:09,659 meso topic ratio and the incoming 633 00:30:15,619 --> 00:30:11,609 material would be an important thing to 634 00:30:18,109 --> 00:30:15,629 know to compare with the n2 gas on the 635 00:30:20,119 --> 00:30:18,119 earth today so I'm going to say this if 636 00:30:21,680 --> 00:30:20,129 the point of today's webinar is to make 637 00:30:23,960 --> 00:30:21,690 sure that we're listing important 638 00:30:26,119 --> 00:30:23,970 questions in the roadmap not necessarily 639 00:30:27,919 --> 00:30:26,129 to answer those questions today so 640 00:30:30,879 --> 00:30:27,929 that's this is a good thing to make sure 641 00:30:32,989 --> 00:30:30,889 is captured in the document that this is 642 00:30:34,669 --> 00:30:32,999 understanding what the Federation 643 00:30:37,399 --> 00:30:34,679 without the topic signatures is likely 644 00:30:38,989 --> 00:30:37,409 to be make sure that that's captured is 645 00:30:42,200 --> 00:30:38,999 research that needs to be done and 646 00:30:45,799 --> 00:30:42,210 Francis a hand raised their present 647 00:30:49,340 --> 00:30:45,809 Gardner yeah I was just going to say 648 00:30:50,960 --> 00:30:49,350 what you just said the questions open I 649 00:30:52,820 --> 00:30:50,970 don't think there is quite an answer I 650 00:30:55,909 --> 00:30:52,830 for earth it's a little complicated 651 00:30:59,570 --> 00:30:55,919 because things have been reset through 652 00:31:02,340 --> 00:30:59,580 geologic time and volatile isotopes are 653 00:31:05,340 --> 00:31:02,350 pretty easy to change 654 00:31:08,690 --> 00:31:05,350 we you know I know that there are very 655 00:31:11,370 --> 00:31:08,700 abilities among at least Mars and Earth 656 00:31:13,260 --> 00:31:11,380 but i'm not sure we know exactly where 657 00:31:16,650 --> 00:31:13,270 those differences come from at this 658 00:31:18,690 --> 00:31:16,660 moment we should just make sure that 659 00:31:20,100 --> 00:31:18,700 when the final version of this document 660 00:31:22,260 --> 00:31:20,110 is written the best captured as a 661 00:31:30,169 --> 00:31:22,270 question that's needing some more 662 00:31:37,919 --> 00:31:33,779 all right so enough said about carbon 663 00:31:42,090 --> 00:31:37,929 and nitrogen i do want to caution people 664 00:31:45,419 --> 00:31:42,100 about the accepting the values that on 665 00:31:50,159 --> 00:31:45,429 the face of them for example these check 666 00:31:54,390 --> 00:31:50,169 marks on the right compare some issues 667 00:31:57,240 --> 00:31:54,400 of bulk IDPs and build to entity and 14 668 00:31:59,720 --> 00:31:57,250 15 is consistent with terrestrial if if 669 00:32:02,039 --> 00:31:59,730 you look at the actual the over the 670 00:32:04,350 --> 00:32:02,049 shown on the left here is kind of an 671 00:32:09,419 --> 00:32:04,360 oval this is from a figure by dominique 672 00:32:12,810 --> 00:32:09,429 pocket lor-van and so essentially the 673 00:32:14,610 --> 00:32:12,820 bulk overlaps the terrestrial value the 674 00:32:16,380 --> 00:32:14,620 mean of course is a little different but 675 00:32:18,720 --> 00:32:16,390 there does there's an issue as to 676 00:32:22,740 --> 00:32:18,730 whether in fact the overlap is 677 00:32:24,180 --> 00:32:22,750 sufficient at the one signal level the 678 00:32:27,270 --> 00:32:24,190 other point to keep in mind is that 679 00:32:30,149 --> 00:32:27,280 thomas ammonia is the principal carrier 680 00:32:32,970 --> 00:32:30,159 volatile nitrogen and we have no idea 681 00:32:35,070 --> 00:32:32,980 what it's 15 nitrogen enrichment maybe 682 00:32:38,490 --> 00:32:35,080 in comets so we really don't even know 683 00:32:41,360 --> 00:32:38,500 how to compare the dominant carrier of 684 00:32:44,610 --> 00:32:41,370 ulta nitrogen comets with the 685 00:32:47,399 --> 00:32:44,620 atmospheric value in the earth the next 686 00:32:49,710 --> 00:32:47,409 point which people often tend over 687 00:32:51,690 --> 00:32:49,720 forget is that the origins of commentary 688 00:32:54,960 --> 00:32:51,700 CNR uncertain which comes up to the 689 00:32:57,470 --> 00:32:54,970 point that was just made namely CN can 690 00:33:01,950 --> 00:32:57,480 impart come from ice like HCM 691 00:33:06,299 --> 00:33:01,960 association of the precursor or from the 692 00:33:07,270 --> 00:33:06,309 rock the dust grains are coral CM jets 693 00:33:09,910 --> 00:33:07,280 and various 694 00:33:12,580 --> 00:33:09,920 correlated with dust grains and so this 695 00:33:15,550 --> 00:33:12,590 raises an issue as to whether the CN is 696 00:33:18,100 --> 00:33:15,560 in fact really a faithful measure of the 697 00:33:20,560 --> 00:33:18,110 overall bulk in a comment or whether 698 00:33:24,220 --> 00:33:20,570 when once we begin to measure ammonia 699 00:33:26,650 --> 00:33:24,230 will see different value and final point 700 00:33:29,350 --> 00:33:26,660 which I mentioned briefly in passing was 701 00:33:31,300 --> 00:33:29,360 the fact that we think that HCN may be 702 00:33:36,900 --> 00:33:31,310 produced from Siena nakoma so to turn 703 00:33:39,370 --> 00:33:36,910 that around an important sub from a 704 00:33:42,070 --> 00:33:39,380 comet and what didn't what proportions 705 00:33:45,100 --> 00:33:42,080 is stored in the nucleus as opposed to 706 00:33:48,460 --> 00:33:45,110 be produced in the coma from reactions 707 00:33:50,650 --> 00:33:48,470 such as cyanogen plus a hydrocarbon such 708 00:33:53,790 --> 00:33:50,660 as methane my question just got typed in 709 00:33:58,300 --> 00:33:53,800 on the cat wonder there okay so we have 710 00:34:00,450 --> 00:33:58,310 is it Ron yes follow talisman syllabus 711 00:34:02,740 --> 00:34:00,460 have similarities what you display for 712 00:34:05,950 --> 00:34:02,750 comments does a suggestive commentary 713 00:34:07,870 --> 00:34:05,960 origin for Enceladus volatiles that I 714 00:34:10,780 --> 00:34:07,880 think is an interesting question one 715 00:34:13,270 --> 00:34:10,790 that we've kicked around here in my 716 00:34:15,370 --> 00:34:13,280 group at Goddard quite a lot my 717 00:34:19,600 --> 00:34:15,380 understanding right now is that hunter 718 00:34:22,270 --> 00:34:19,610 wait who is the P I on the instrument 719 00:34:27,130 --> 00:34:22,280 that's measured these volatiles from 720 00:34:31,870 --> 00:34:27,140 Cassini now things that essentially most 721 00:34:36,000 --> 00:34:31,880 or even all of the smaller molecules can 722 00:34:39,240 --> 00:34:36,010 be derived by destruction of benzene and 723 00:34:42,909 --> 00:34:39,250 most of what they see as hydrocarbons 724 00:34:45,340 --> 00:34:42,919 there is some water and so it's not 725 00:34:48,010 --> 00:34:45,350 clear to me now even what is being 726 00:34:50,880 --> 00:34:48,020 released from Enceladus because by the 727 00:34:54,940 --> 00:34:50,890 time you measure something in the plumes 728 00:34:57,580 --> 00:34:54,950 it could have only a in direct relation 729 00:34:59,920 --> 00:34:57,590 to the material that actually was being 730 00:35:04,630 --> 00:34:59,930 released from the base of the plume 731 00:35:06,490 --> 00:35:04,640 itself so but nevertheless the idea of 732 00:35:08,950 --> 00:35:06,500 the cometary origin foreign solidus has 733 00:35:10,180 --> 00:35:08,960 been suggested 734 00:35:12,000 --> 00:35:10,190 I think it's actually even in the 735 00:35:15,670 --> 00:35:12,010 literature but I think we don't have the 736 00:35:19,780 --> 00:35:15,680 hard evidence yet to test that 737 00:35:21,609 --> 00:35:19,790 hypothesis so that's something that one 738 00:35:23,650 --> 00:35:21,619 would like to do and of course now that 739 00:35:27,370 --> 00:35:23,660 we know there are plumes of water on 740 00:35:30,370 --> 00:35:27,380 Europa at the South Pole which was just 741 00:35:32,829 --> 00:35:30,380 published in science we'd like to know 742 00:35:38,980 --> 00:35:32,839 whether other species are being released 743 00:35:43,750 --> 00:35:38,990 as well ok so now comparing these two 744 00:35:46,990 --> 00:35:43,760 metrics has been done by sanaka and 745 00:35:50,520 --> 00:35:47,000 allocated company and what's interesting 746 00:35:53,500 --> 00:35:50,530 is that suddenly what you see is that 747 00:35:55,990 --> 00:35:53,510 for a variety of comets and these by the 748 00:35:58,540 --> 00:35:56,000 way are grouped by orbiting blast and 749 00:36:01,390 --> 00:35:58,550 dissemination areas we get good 750 00:36:04,720 --> 00:36:01,400 correlation between opr clustering and 751 00:36:07,390 --> 00:36:04,730 the isotopic ratio of nitrogen but there 752 00:36:10,089 --> 00:36:07,400 is one comet these are two fragments of 753 00:36:13,450 --> 00:36:10,099 Russian Blackmon 3 which is an ecliptic 754 00:36:15,010 --> 00:36:13,460 comet that's lit they're totally 755 00:36:17,829 --> 00:36:15,020 different so it's quite of something 756 00:36:20,020 --> 00:36:17,839 going on we don't understand and until 757 00:36:22,060 --> 00:36:20,030 we do understand it we can't assess this 758 00:36:24,490 --> 00:36:22,070 take this is a metric to assess what 759 00:36:27,010 --> 00:36:24,500 might be delivered to the earth now 760 00:36:30,099 --> 00:36:27,020 let's just touch on hydrogen and the d2h 761 00:36:33,160 --> 00:36:30,109 ratio because this is a key metric for 762 00:36:35,859 --> 00:36:33,170 many studies not just for commentary 763 00:36:39,400 --> 00:36:35,869 Isis and so on this is this is work done 764 00:36:42,700 --> 00:36:39,410 by Olivier mousses and in fact on the 765 00:36:44,200 --> 00:36:42,710 right panel of showing the d2h ratio is 766 00:36:47,970 --> 00:36:44,210 a function of distance from the young 767 00:36:52,660 --> 00:36:47,980 son and this already incorporated 768 00:36:55,300 --> 00:36:52,670 something like five to fourteen au which 769 00:36:56,890 --> 00:36:55,310 was the region for the giant planets at 770 00:37:00,130 --> 00:36:56,900 the beginning of the nice model 771 00:37:02,680 --> 00:37:00,140 dynamical simulation we already know 772 00:37:05,079 --> 00:37:02,690 from the case of Saturn what the beast 773 00:37:07,930 --> 00:37:05,089 no value is its basis i'm sorry what the 774 00:37:10,780 --> 00:37:07,940 dth ratio is it's been measured to be be 775 00:37:13,740 --> 00:37:10,790 slow and methane very accurately 776 00:37:18,000 --> 00:37:13,750 untighten so it's right about where the 777 00:37:20,220 --> 00:37:18,010 arrow is now right about there drupal 778 00:37:23,640 --> 00:37:20,230 is usually taken to be the nebular value 779 00:37:26,490 --> 00:37:23,650 and that's a roughly two times 7-5 I 780 00:37:29,880 --> 00:37:26,500 don't know why he has this would be a 781 00:37:31,740 --> 00:37:29,890 water model at the position of Jupiter 782 00:37:34,950 --> 00:37:31,750 but of course Jupiter itself is really 783 00:37:40,430 --> 00:37:34,960 dominated by hydrogen which is from the 784 00:37:44,130 --> 00:37:40,440 nebula was taken as the value for nebula 785 00:37:45,810 --> 00:37:44,140 is it for comments the issue is how do 786 00:37:49,590 --> 00:37:45,820 they compare with the terrestrial water 787 00:37:52,670 --> 00:37:49,600 and if you ask that question three years 788 00:37:56,760 --> 00:37:52,680 ago the answer would have been 789 00:37:59,790 --> 00:37:56,770 encompassed by this lips to the right 790 00:38:02,190 --> 00:37:59,800 here that for total of seven comets the 791 00:38:04,590 --> 00:38:02,200 mean value is twice enriched relative to 792 00:38:09,150 --> 00:38:04,600 terrestrial water and so this led people 793 00:38:11,220 --> 00:38:09,160 to assess the possibility of delivery of 794 00:38:14,220 --> 00:38:11,230 our associates by cometary impact is 795 00:38:16,110 --> 00:38:14,230 being quite small affleck roughly ten 796 00:38:20,010 --> 00:38:16,120 percent of her ass ocean water could 797 00:38:23,400 --> 00:38:20,020 come from comets of this type what and 798 00:38:25,800 --> 00:38:23,410 when Hartley 2 was active Herschel 799 00:38:28,290 --> 00:38:25,810 measured the D to weight ratio and water 800 00:38:30,540 --> 00:38:28,300 released from hardly to which is a 801 00:38:33,300 --> 00:38:30,550 Kuiper belt object and bingo it was 802 00:38:37,020 --> 00:38:33,310 exactly coincident with the value of 803 00:38:40,560 --> 00:38:37,030 east mall with in error and so at this 804 00:38:43,020 --> 00:38:40,570 point people who know little about comet 805 00:38:44,940 --> 00:38:43,030 said aha this could mean that you know 806 00:38:48,090 --> 00:38:44,950 comets are responsible for its oceans 807 00:38:51,570 --> 00:38:48,100 after all but the real issue here is 808 00:38:53,640 --> 00:38:51,580 that one comet does not make a mean we 809 00:38:57,780 --> 00:38:53,650 don't really know what the diversity of 810 00:39:00,120 --> 00:38:57,790 do H is within Kuiper belt population if 811 00:39:02,070 --> 00:39:00,130 you don't know what the mean value is we 812 00:39:03,840 --> 00:39:02,080 we know something more about where those 813 00:39:05,900 --> 00:39:03,850 bodies came from and how they were 814 00:39:08,940 --> 00:39:05,910 delivered to the Kuiper belt through the 815 00:39:10,590 --> 00:39:08,950 dynamical models Oh yet don't know how 816 00:39:12,330 --> 00:39:10,600 many of those bodies could have been 817 00:39:15,630 --> 00:39:12,340 delivered to the terrestrial planets 818 00:39:18,450 --> 00:39:15,640 during that event so there are those two 819 00:39:22,890 --> 00:39:18,460 things that are some questions that need 820 00:39:24,100 --> 00:39:22,900 a significant work in order to help to 821 00:39:26,740 --> 00:39:24,110 assess 822 00:39:31,450 --> 00:39:26,750 a question of where deters get its water 823 00:39:34,150 --> 00:39:31,460 and it's organic inventory so I've kind 824 00:39:37,930 --> 00:39:34,160 of captured those caveats and cautions 825 00:39:39,040 --> 00:39:37,940 here you can look at those at your 826 00:39:41,890 --> 00:39:39,050 letter I don't want to take any more 827 00:39:46,240 --> 00:39:41,900 time at this point to do it let's move 828 00:39:48,100 --> 00:39:46,250 on towards the refractory material and I 829 00:39:50,170 --> 00:39:48,110 have just two slides on comets and then 830 00:39:51,910 --> 00:39:50,180 Jamie's going to take over and because 831 00:39:56,400 --> 00:39:51,920 she has much more to say about this 832 00:39:59,790 --> 00:39:56,410 stuver and her colleagues work on the 833 00:40:02,800 --> 00:39:59,800 organics and primitive meteorites and 834 00:40:06,550 --> 00:40:02,810 and in the start of samples but 835 00:40:10,170 --> 00:40:06,560 fundamentally crystal silicates come in 836 00:40:13,450 --> 00:40:10,180 two forms crystalline or amorphous and 837 00:40:16,510 --> 00:40:13,460 it's been a mantra for a long time that 838 00:40:19,660 --> 00:40:16,520 if one sees crystal and silicates and 839 00:40:22,660 --> 00:40:19,670 comets they must have come from the near 840 00:40:26,730 --> 00:40:22,670 Sun location and this applies outward 841 00:40:31,690 --> 00:40:29,230 protoplanetary disk to the outer comet 842 00:40:34,030 --> 00:40:31,700 forming region that was of course the 843 00:40:37,570 --> 00:40:34,040 natural when comet when the giant 844 00:40:40,360 --> 00:40:37,580 planets didn't move around when comets 845 00:40:44,260 --> 00:40:40,370 were always formed far from the young 846 00:40:46,300 --> 00:40:44,270 son or evolve son and so on so this also 847 00:40:48,940 --> 00:40:46,310 has to be re-examined in the light of 848 00:40:51,610 --> 00:40:48,950 all these new models and so on but 849 00:40:53,730 --> 00:40:51,620 nevertheless it is interesting that the 850 00:40:56,740 --> 00:40:53,740 crystal silicates have been seen in 851 00:40:59,020 --> 00:40:56,750 comets that have origin in the Kuiper 852 00:41:00,360 --> 00:40:59,030 belt that's where they form does it mean 853 00:41:02,470 --> 00:41:00,370 where the dust form to where the 854 00:41:05,980 --> 00:41:02,480 volatiles condense but that's where the 855 00:41:11,410 --> 00:41:05,990 comet itself formed so this presents a 856 00:41:13,680 --> 00:41:11,420 major in itself now the mineralogy of 857 00:41:17,230 --> 00:41:13,690 those dust particles is the other 858 00:41:21,780 --> 00:41:17,240 interesting part of that some inclusions 859 00:41:23,890 --> 00:41:21,790 have been used to identify interstellar 860 00:41:26,680 --> 00:41:23,900 particles that were included within the 861 00:41:27,740 --> 00:41:26,690 return common sense others are nebular 862 00:41:29,720 --> 00:41:27,750 origin and 863 00:41:31,790 --> 00:41:29,730 I think Jamie will say a lot more about 864 00:41:35,090 --> 00:41:31,800 that but just to stick with the 865 00:41:36,950 --> 00:41:35,100 silicates for a minute the the Carnegie 866 00:41:42,410 --> 00:41:36,960 group is and others have demonstrated 867 00:41:45,230 --> 00:41:42,420 that the dust in comet Bill 2 is formed 868 00:41:48,230 --> 00:41:45,240 within probably about seven solar radii 869 00:41:50,540 --> 00:41:48,240 have the young son so that stuff is 870 00:41:52,700 --> 00:41:50,550 definitely not interstellar up for some 871 00:41:57,110 --> 00:41:52,710 of the high nitrogen 15 inclusions 872 00:42:00,230 --> 00:41:57,120 perhaps so I think why don't you go 873 00:42:03,080 --> 00:42:00,240 ahead actually try to keep my comments 874 00:42:05,330 --> 00:42:03,090 very brief and it's focused on some of 875 00:42:08,240 --> 00:42:05,340 the questions in this road map document 876 00:42:09,710 --> 00:42:08,250 that address delivery of organics by icy 877 00:42:12,200 --> 00:42:09,720 bodies and the chemistry with you on an 878 00:42:15,020 --> 00:42:12,210 icy bodies in order to do that I went to 879 00:42:17,150 --> 00:42:15,030 looking at meteorites as well part of 880 00:42:18,890 --> 00:42:17,160 this is because analysis of organic 881 00:42:21,560 --> 00:42:18,900 compounds in comets had been primarily 882 00:42:23,600 --> 00:42:21,570 limited to volatile and spectroscopic 883 00:42:25,670 --> 00:42:23,610 measurements that can be made with the 884 00:42:27,110 --> 00:42:25,680 exception of the material returned by 885 00:42:31,400 --> 00:42:27,120 the Stardust mission from the ville to 886 00:42:33,020 --> 00:42:31,410 coma the startups allowed us to get a 887 00:42:35,300 --> 00:42:33,030 little bit of more compound specific 888 00:42:37,250 --> 00:42:35,310 organic identification of some of the 889 00:42:40,130 --> 00:42:37,260 complex organics for example the amino 890 00:42:42,260 --> 00:42:40,140 acid glycine was detected but there's 891 00:42:45,020 --> 00:42:42,270 still a lot we don't know about the 892 00:42:47,360 --> 00:42:45,030 prebiotic chemistry some of the larger 893 00:42:49,550 --> 00:42:47,370 organics that might be present in these 894 00:42:52,750 --> 00:42:49,560 icy bodies and this road map document is 895 00:42:55,550 --> 00:42:52,760 talking about the potential delivery of 896 00:42:58,970 --> 00:42:55,560 this type of material from RC bodies and 897 00:43:01,070 --> 00:42:58,980 from other meteorites to the early Earth 898 00:43:03,020 --> 00:43:01,080 so I thought it looks just a little bit 899 00:43:05,270 --> 00:43:03,030 at some of what we know about meteoritic 900 00:43:06,980 --> 00:43:05,280 organics what clues they give us about 901 00:43:08,630 --> 00:43:06,990 the type of prebiotic chemistry that 902 00:43:11,750 --> 00:43:08,640 might be going on in these bodies and 903 00:43:14,800 --> 00:43:11,760 what questions shall remain that we hope 904 00:43:17,360 --> 00:43:14,810 the roadmap will address in the future 905 00:43:19,070 --> 00:43:17,370 so I wanted to point out here that most 906 00:43:21,440 --> 00:43:19,080 of the organic studies that have been 907 00:43:26,350 --> 00:43:21,450 done on meteorites are on carbonaceous 908 00:43:30,740 --> 00:43:26,360 chondrite which let's do this my pointer 909 00:43:33,020 --> 00:43:30,750 which are subdivided into a sub groups 910 00:43:35,030 --> 00:43:33,030 here and the work that's been done 911 00:43:37,700 --> 00:43:35,040 looking at organic inventory of these 912 00:43:41,360 --> 00:43:37,710 carbonaceous chondrites has shown a lot 913 00:43:43,310 --> 00:43:41,370 of variation among these subgroups 914 00:43:45,350 --> 00:43:43,320 and we don't really know where the icy 915 00:43:47,570 --> 00:43:45,360 bodies will necessarily said what type 916 00:43:49,160 --> 00:43:47,580 of chemistry is going on there there are 917 00:43:50,990 --> 00:43:49,170 similarities between all these subgroups 918 00:43:53,360 --> 00:43:51,000 but also some differences deadly 919 00:43:55,010 --> 00:43:53,370 questions lead to questions we do you 920 00:43:57,370 --> 00:43:55,020 think that the CI carbonaceous 921 00:44:00,080 --> 00:43:57,380 chondrites may be the most similar to 922 00:44:01,280 --> 00:44:00,090 icy bodies there the carbonaceous 923 00:44:04,370 --> 00:44:01,290 chondrites that have seen the most 924 00:44:06,170 --> 00:44:04,380 aqueous alteration liquid water present 925 00:44:07,760 --> 00:44:06,180 on the parent body so there's a 926 00:44:10,490 --> 00:44:07,770 suggestion that they may be related to 927 00:44:14,000 --> 00:44:10,500 comets and two other icy bodies and I'll 928 00:44:15,830 --> 00:44:14,010 show you a little bit about how that 929 00:44:19,820 --> 00:44:15,840 mainly just some differences in the 930 00:44:22,310 --> 00:44:19,830 organic compounds that are produced but 931 00:44:24,590 --> 00:44:22,320 just to start looking at some of the 932 00:44:26,210 --> 00:44:24,600 diversity that might exist this is 933 00:44:28,820 --> 00:44:26,220 looking at the merchants and meteorite 934 00:44:31,190 --> 00:44:28,830 which is a cm2 carbonaceous chondrite 935 00:44:32,780 --> 00:44:31,200 it's the carbonaceous chondrite that's 936 00:44:35,510 --> 00:44:32,790 been the most heavily studied for 937 00:44:38,810 --> 00:44:35,520 organics and what we find is a very wide 938 00:44:40,580 --> 00:44:38,820 diversity of organic compound a lot of 939 00:44:43,370 --> 00:44:40,590 insoluble organic matter is it's 940 00:44:45,170 --> 00:44:43,380 macromolecular material but also quite a 941 00:44:47,330 --> 00:44:45,180 number of different compound classes in 942 00:44:49,040 --> 00:44:47,340 the soluble organic matter and I've 943 00:44:51,620 --> 00:44:49,050 highlighted just a couple of compound 944 00:44:54,020 --> 00:44:51,630 classes they're irrelevant astrobiology 945 00:44:56,240 --> 00:44:54,030 roadmap to understanding the origin of 946 00:44:58,820 --> 00:44:56,250 the compounds relevant for the origin of 947 00:45:01,760 --> 00:44:58,830 life so things such as amino acids 948 00:45:03,650 --> 00:45:01,770 amines purines pyrimidines and heck 949 00:45:06,080 --> 00:45:03,660 nitrogen heterocycles things like that 950 00:45:08,480 --> 00:45:06,090 and we see that there are there's a 951 00:45:11,030 --> 00:45:08,490 large amount of these types of molecules 952 00:45:14,390 --> 00:45:11,040 there's a rich prebiotic chemistry going 953 00:45:16,670 --> 00:45:14,400 on here and in fact recent studies of 954 00:45:18,770 --> 00:45:16,680 the soluble material showed that there's 955 00:45:20,810 --> 00:45:18,780 likely millions of different structures 956 00:45:23,060 --> 00:45:20,820 of diverse structures of organic 957 00:45:25,280 --> 00:45:23,070 compounds in the merchants and meteorite 958 00:45:27,620 --> 00:45:25,290 and so when we learn from this if we're 959 00:45:30,080 --> 00:45:27,630 looking at the potential delivery of 960 00:45:32,000 --> 00:45:30,090 organics from primitive icy bodies that 961 00:45:34,970 --> 00:45:32,010 impacted the early Earth or other young 962 00:45:37,130 --> 00:45:34,980 planets is that a very large diversity 963 00:45:42,680 --> 00:45:37,140 of these compounds necessary for life 964 00:45:44,240 --> 00:45:42,690 could have been delivered and if we 965 00:45:47,510 --> 00:45:44,250 focus in a little bit on some of the 966 00:45:49,940 --> 00:45:47,520 molecules that we care about a lot for 967 00:45:50,430 --> 00:45:49,950 life on earth we can look at amino acids 968 00:45:52,890 --> 00:45:50,440 and it 969 00:45:54,750 --> 00:45:52,900 in clio basis animate alas as we know 970 00:45:56,609 --> 00:45:54,760 are the building blocks of proteins and 971 00:45:59,370 --> 00:45:56,619 enzymes and serve a lot of important 972 00:46:01,829 --> 00:45:59,380 roles in life on earth one of the 973 00:46:04,559 --> 00:46:01,839 mysteries or interesting factors about 974 00:46:06,980 --> 00:46:04,569 them is that amino acids are chiral that 975 00:46:09,510 --> 00:46:06,990 is amino acid molecules exist in two 976 00:46:12,930 --> 00:46:09,520 non-superimposable mirror image forms 977 00:46:15,089 --> 00:46:12,940 like your hands abiotic chemistry forms 978 00:46:16,710 --> 00:46:15,099 equal amounts of the two we get racemic 979 00:46:18,960 --> 00:46:16,720 mixture is equal amount to the left and 980 00:46:21,030 --> 00:46:18,970 right hand but life on Earth uses almost 981 00:46:23,819 --> 00:46:21,040 exclusively the left-handed form of 982 00:46:26,069 --> 00:46:23,829 these molecules and the way that life 983 00:46:27,870 --> 00:46:26,079 went but that chemistry went from 984 00:46:29,760 --> 00:46:27,880 producing the sequel mixtures to life 985 00:46:32,430 --> 00:46:29,770 using specifically the left-handed is a 986 00:46:34,559 --> 00:46:32,440 big question in astrobiology research 987 00:46:36,960 --> 00:46:34,569 and origin of life research what is the 988 00:46:39,059 --> 00:46:36,970 origin of that biological homo chirality 989 00:46:40,920 --> 00:46:39,069 and I'll show you in a minute what we 990 00:46:43,020 --> 00:46:40,930 might learn from meteorites about it and 991 00:46:45,960 --> 00:46:43,030 how that extrapolate to some of these 992 00:46:48,530 --> 00:46:45,970 icy bodies I also point out nucleobases 993 00:46:52,770 --> 00:46:48,540 because a range of nuclear bases and nut 994 00:46:54,780 --> 00:46:52,780 similar compounds have been shown I've 995 00:46:59,550 --> 00:46:54,790 been detected in carbonaceous chondrite 996 00:47:01,800 --> 00:46:59,560 you just went and I showed your a 997 00:47:04,800 --> 00:47:01,810 variety of compounds some of which like 998 00:47:08,339 --> 00:47:04,810 a demain and guanine are used in DNA and 999 00:47:10,050 --> 00:47:08,349 RNA I'm in life on earth but also some 1000 00:47:12,420 --> 00:47:10,060 alternate structures that are produced 1001 00:47:15,359 --> 00:47:12,430 by about a chemistry and show up in 1002 00:47:17,910 --> 00:47:15,369 these meteorites but aren't used much in 1003 00:47:19,740 --> 00:47:17,920 life and so that types of a final point 1004 00:47:22,380 --> 00:47:19,750 on that slide which is that there's 1005 00:47:25,410 --> 00:47:22,390 prebiotic chemistry that occurred on icy 1006 00:47:27,390 --> 00:47:25,420 bodies on rocky bodies can produce a 1007 00:47:29,700 --> 00:47:27,400 very large chemical diversity compared 1008 00:47:32,819 --> 00:47:29,710 to the specificity used in biology and 1009 00:47:35,150 --> 00:47:32,829 that's not own question of interest of 1010 00:47:37,260 --> 00:47:35,160 astrobiology roadmap I think does 1011 00:47:39,510 --> 00:47:37,270 understanding the diversity and the 1012 00:47:41,430 --> 00:47:39,520 distribution of these chemicals produced 1013 00:47:43,980 --> 00:47:41,440 in probiotic environments or on icy 1014 00:47:46,829 --> 00:47:43,990 bodies help us understand the origin of 1015 00:47:48,960 --> 00:47:46,839 the biological specificity why life uses 1016 00:47:52,319 --> 00:47:48,970 only the left-handed amino acids or 1017 00:47:53,670 --> 00:47:52,329 certain nuclear bases and this actually 1018 00:47:56,250 --> 00:47:53,680 came up a little bit in some of the 1019 00:47:58,350 --> 00:47:56,260 other roadmap webinars that have half 1020 00:48:00,510 --> 00:47:58,360 already particularly we had an earlier 1021 00:48:02,370 --> 00:48:00,520 one about sources of organic monomers 1022 00:48:06,120 --> 00:48:02,380 and some of these same questions were 1023 00:48:08,910 --> 00:48:06,130 released there we have two more slides I 1024 00:48:12,300 --> 00:48:08,920 think this one is just showing that 1025 00:48:13,950 --> 00:48:12,310 amino acid abundant varies across meteor 1026 00:48:18,240 --> 00:48:13,960 our class of us we have ten minutes left 1027 00:48:21,840 --> 00:48:18,250 so okay what I wanted to point out here 1028 00:48:24,510 --> 00:48:21,850 is that my pointer will go on the left 1029 00:48:27,210 --> 00:48:24,520 side here our meteorites that have been 1030 00:48:28,470 --> 00:48:27,220 extensively a curiously altered they 1031 00:48:30,570 --> 00:48:28,480 were exposed to a lot of liquid water 1032 00:48:32,790 --> 00:48:30,580 and their parent body let me go to about 1033 00:48:35,310 --> 00:48:32,800 here these meteorites have seen much 1034 00:48:37,170 --> 00:48:35,320 less water on their parent body and this 1035 00:48:39,390 --> 00:48:37,180 is a logarithmic scale of amino acid 1036 00:48:41,730 --> 00:48:39,400 abundant we see that the amino acid 1037 00:48:43,800 --> 00:48:41,740 abundance is quite sensitive to the 1038 00:48:48,900 --> 00:48:43,810 amount of aqueous alteration on the 1039 00:48:50,970 --> 00:48:48,910 parent body and I think that that gives 1040 00:48:52,980 --> 00:48:50,980 us something to look at as we start to 1041 00:48:54,720 --> 00:48:52,990 hopefully be able to examine organic 1042 00:48:58,260 --> 00:48:54,730 inventory and comments with future 1043 00:49:00,240 --> 00:48:58,270 comments sample return missions whether 1044 00:49:02,040 --> 00:49:00,250 these icy bodies where there's more 1045 00:49:04,170 --> 00:49:02,050 Equus alteration work potential for 1046 00:49:05,670 --> 00:49:04,180 liquid water interactions would affect 1047 00:49:09,900 --> 00:49:05,680 the abundance and distribution of 1048 00:49:13,500 --> 00:49:09,910 compounds that we see and the last point 1049 00:49:14,970 --> 00:49:13,510 I wanted to raise as a question that may 1050 00:49:17,610 --> 00:49:14,980 be of interest for the roadmap and 1051 00:49:21,180 --> 00:49:17,620 future research is going back that homo 1052 00:49:22,800 --> 00:49:21,190 chirality question abiotic chemistry 1053 00:49:25,140 --> 00:49:22,810 produces equal amounts of left and 1054 00:49:26,760 --> 00:49:25,150 right-handed most amino acids and most 1055 00:49:29,040 --> 00:49:26,770 meteorites that have been studied are 1056 00:49:33,120 --> 00:49:29,050 also racemic we see equal amounts to the 1057 00:49:35,460 --> 00:49:33,130 left and right but left-handed excesses 1058 00:49:38,370 --> 00:49:35,470 have been identified in some amino acids 1059 00:49:40,080 --> 00:49:38,380 in some meteorites and this plot began 1060 00:49:43,020 --> 00:49:40,090 is showing the correlation of those 1061 00:49:45,420 --> 00:49:43,030 excesses with aqueous alteration on the 1062 00:49:47,460 --> 00:49:45,430 parent body and again meteorites on the 1063 00:49:50,520 --> 00:49:47,470 left here these are just looking at the 1064 00:49:52,980 --> 00:49:50,530 percent of left-handed access in everest 1065 00:49:54,630 --> 00:49:52,990 amino acid i serve a lead in a variety 1066 00:49:57,150 --> 00:49:54,640 of meteorites the ones on the Left have 1067 00:49:59,100 --> 00:49:57,160 seen more aqueous alteration and also 1068 00:50:02,400 --> 00:49:59,110 show more of this left-handed excess and 1069 00:50:05,880 --> 00:50:02,410 so we wonder whether there are processes 1070 00:50:07,259 --> 00:50:05,890 on these icy bodies in these areas were 1071 00:50:09,329 --> 00:50:07,269 provided chemistry 1072 00:50:11,729 --> 00:50:09,339 been exposed to a grease alteration that 1073 00:50:13,919 --> 00:50:11,739 might have amplified in excess of 1074 00:50:15,389 --> 00:50:13,929 left-handed amino acids but then might 1075 00:50:17,759 --> 00:50:15,399 have been delivered to the early Earth 1076 00:50:20,149 --> 00:50:17,769 or to other planetary surfaces and in 1077 00:50:22,919 --> 00:50:20,159 some way helped to seed that origin of 1078 00:50:27,509 --> 00:50:22,929 biological homo chirality so this is a 1079 00:50:30,899 --> 00:50:27,519 question for for future research I see 1080 00:50:34,169 --> 00:50:30,909 Doug just asked about measuring Carol 1081 00:50:36,359 --> 00:50:34,179 accesses and comments I'm waiting for 1082 00:50:38,819 --> 00:50:36,369 Thomas sample return for that to happen 1083 00:50:40,679 --> 00:50:38,829 i think i'm not sure i don't know of any 1084 00:50:44,759 --> 00:50:40,689 way to be able to measure that remotely 1085 00:50:47,789 --> 00:50:44,769 the chiral accesses it's correct that 1086 00:50:50,549 --> 00:50:47,799 there's no tyrol measurement capability 1087 00:50:52,709 --> 00:50:50,559 and rosette correct yeah I'm pretty sure 1088 00:50:57,839 --> 00:50:52,719 the correct Aleta yes so we really need 1089 00:50:59,729 --> 00:50:57,849 either institue measurements and comets 1090 00:51:01,739 --> 00:50:59,739 which have a sort of chromatography that 1091 00:51:03,329 --> 00:51:01,749 can do chiro measurements or bringing 1092 00:51:05,880 --> 00:51:03,339 samples back and being able to do those 1093 00:51:07,409 --> 00:51:05,890 measurements here and I see penny asking 1094 00:51:09,929 --> 00:51:07,419 about destruction organics during entry 1095 00:51:12,359 --> 00:51:09,939 and impact on to the receiving target Oh 1096 00:51:15,929 --> 00:51:12,369 would I see materials be more or less 1097 00:51:18,120 --> 00:51:15,939 likely that's a good question that's not 1098 00:51:19,859 --> 00:51:18,130 what I've thought about much mike has 1099 00:51:22,499 --> 00:51:19,869 something to say about it yeah I would 1100 00:51:26,329 --> 00:51:22,509 like to comment on that you know the 1101 00:51:32,969 --> 00:51:26,339 real issue is the entry process its size 1102 00:51:34,829 --> 00:51:32,979 has benefits from breakup of the body if 1103 00:51:37,109 --> 00:51:34,839 you bring in a body that's a kilometer 1104 00:51:39,569 --> 00:51:37,119 diameter it pretty much is going to hit 1105 00:51:41,819 --> 00:51:39,579 the ground before it breaks up but when 1106 00:51:45,889 --> 00:51:41,829 you get to maybe a hundred meters or 1107 00:51:49,859 --> 00:51:45,899 less than the pressure wave which the 1108 00:51:53,309 --> 00:51:49,869 body encounters as the shock builds up 1109 00:51:57,209 --> 00:51:53,319 on entry will in fact cause a disruption 1110 00:52:00,209 --> 00:51:57,219 but it depends on the binding energy of 1111 00:52:02,789 --> 00:52:00,219 the material itself so for example a 1112 00:52:06,409 --> 00:52:02,799 rock like a meteorite that reaches the 1113 00:52:09,659 --> 00:52:06,419 ground may have a binding energy that's 1114 00:52:13,339 --> 00:52:09,669 something on the order of maybe 10,000 1115 00:52:15,210 --> 00:52:13,349 dynes per square centimeter whereas a 1116 00:52:17,940 --> 00:52:15,220 comet nucleus 1117 00:52:20,820 --> 00:52:17,950 a binding energy that is much much 1118 00:52:22,589 --> 00:52:20,830 smaller hundred times at least and so 1119 00:52:26,430 --> 00:52:22,599 the comet nucleus is going to actually 1120 00:52:29,640 --> 00:52:26,440 be broken up fairly easily and the 1121 00:52:32,790 --> 00:52:29,650 fragments will be decelerated quite 1122 00:52:34,830 --> 00:52:32,800 easily and they will essentially reach 1123 00:52:38,280 --> 00:52:34,840 the ground pretty much intact and 1124 00:52:40,500 --> 00:52:38,290 deliver their organics as they as they 1125 00:52:42,690 --> 00:52:40,510 do that the stone is like the 1126 00:52:45,420 --> 00:52:42,700 carbonaceous chondrites and so on and 1127 00:52:47,940 --> 00:52:45,430 merchants and so on those those bodies 1128 00:52:51,109 --> 00:52:47,950 reach the ground is pregnant sat at 1129 00:52:54,660 --> 00:52:51,119 range in size from elana meters 1130 00:52:56,820 --> 00:52:54,670 millimeters to meters and they also 1131 00:53:00,690 --> 00:52:56,830 deliver their materials to the ground 1132 00:53:03,599 --> 00:53:00,700 intact but it's the small particles that 1133 00:53:05,810 --> 00:53:03,609 are entering say own sizes on the order 1134 00:53:07,950 --> 00:53:05,820 of millimeters and so on like IDPs 1135 00:53:09,510 --> 00:53:07,960 basically are going to lose almost all 1136 00:53:12,990 --> 00:53:09,520 their organics because they get super 1137 00:53:15,089 --> 00:53:13,000 heated and even get vaporized and so on 1138 00:53:17,040 --> 00:53:15,099 it I said no we're running out of time 1139 00:53:19,740 --> 00:53:17,050 here I just want to say I noted that 1140 00:53:22,109 --> 00:53:19,750 down it has perhaps something against 1141 00:53:25,109 --> 00:53:22,119 you included in the road map document 1142 00:53:28,290 --> 00:53:25,119 that they're gonna think I'm noting some 1143 00:53:30,109 --> 00:53:28,300 of this down the document I will make 1144 00:53:31,950 --> 00:53:30,119 sure that that gets into the final 1145 00:53:34,260 --> 00:53:31,960 documented some vets to go to the 1146 00:53:36,540 --> 00:53:34,270 roadmap no these are very very valuable 1147 00:53:38,370 --> 00:53:36,550 college yeah it's the point of this is 1148 00:53:40,980 --> 00:53:38,380 to come up with the where we want to go 1149 00:53:42,859 --> 00:53:40,990 as research for the next ten years it's 1150 00:53:45,480 --> 00:53:42,869 very good to have these comments now 1151 00:53:47,579 --> 00:53:45,490 Andy Mike I suppose someone's going to 1152 00:53:51,480 --> 00:53:47,589 send us this list of comments is that 1153 00:53:54,420 --> 00:53:51,490 right it is you can never comments but 1154 00:53:56,160 --> 00:53:54,430 given that we are just coming to the top 1155 00:53:59,130 --> 00:53:56,170 of the hour I was going to take a moment 1156 00:54:01,290 --> 00:53:59,140 to to mention to people that the the 1157 00:54:04,650 --> 00:54:01,300 document that this presentation is based 1158 00:54:06,720 --> 00:54:04,660 on is now open for comments just in case 1159 00:54:08,460 --> 00:54:06,730 any of the people present or anyone 1160 00:54:11,070 --> 00:54:08,470 listening to this hasn't done that 1161 00:54:12,930 --> 00:54:11,080 before all you have to do is click on 1162 00:54:15,300 --> 00:54:12,940 the link and that will take you straight 1163 00:54:18,660 --> 00:54:15,310 to the Google document we do request 1164 00:54:21,390 --> 00:54:18,670 that if you have a google ID login with 1165 00:54:24,190 --> 00:54:21,400 them purely because it helps the authors 1166 00:54:25,900 --> 00:54:24,200 then see who's making which comment if 1167 00:54:29,050 --> 00:54:25,910 don't have a Google idea if you could 1168 00:54:32,530 --> 00:54:29,060 just note your name down on the comments 1169 00:54:35,200 --> 00:54:32,540 in case they need to get active and just 1170 00:54:38,200 --> 00:54:35,210 to be clear the overall process exactly 1171 00:54:40,180 --> 00:54:38,210 as we've been doing here is to note any 1172 00:54:43,030 --> 00:54:40,190 questions or ideas that could help 1173 00:54:45,130 --> 00:54:43,040 strengthen the paper because we are 1174 00:54:47,170 --> 00:54:45,140 coming to the end of the process we 1175 00:54:49,480 --> 00:54:47,180 still have a few weeks for people feel 1176 00:54:52,030 --> 00:54:49,490 to put their comments in but now would 1177 00:54:53,710 --> 00:54:52,040 be a great time to do it so we'd 1178 00:54:56,170 --> 00:54:53,720 encourage you to go back to the paper 1179 00:54:58,420 --> 00:54:56,180 insert any comments on there and yes 1180 00:55:02,349 --> 00:54:58,430 everything that's been entered into the 1181 00:55:05,170 --> 00:55:02,359 chat box will also be available now are 1182 00:55:07,180 --> 00:55:05,180 there any last questions or the 1183 00:55:09,579 --> 00:55:07,190 presenters need to to make any last 1184 00:55:11,910 --> 00:55:09,589 comments before we wrap it up this is 1185 00:55:16,120 --> 00:55:11,920 the last slide at my cabbage some 1186 00:55:18,760 --> 00:55:16,130 references there y plus we're going to 1187 00:55:21,220 --> 00:55:18,770 post a bibliography and so on and our 1188 00:55:23,740 --> 00:55:21,230 next to go around so I think that will 1189 00:55:28,109 --> 00:55:23,750 help people somewhat getting back into 1190 00:55:33,520 --> 00:55:30,609 excellent well in that case thank you 1191 00:55:36,250 --> 00:55:33,530 very much for a great presentation and 1192 00:55:38,260 --> 00:55:36,260 we hope to see everybody's comments 1193 00:55:40,680 --> 00:55:38,270 being popped in to the google document